Đốt cháy hoàn toàn hỗn hợp hai amin no, đơn chức, là đồng đẳng liên tiếp, thu được 2,24 lít khí CO2 (đktc) và 3,6 gam H2O. Công thức phân tử của 2 amin là
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Lời giải:
Báo saiSơ đồ phản ứng :
\(\begin{array}{*{20}{c}} {}&{{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {C_{\bar n}}{H_{2\bar n\, + \,3}}N{\mkern 1mu} {\mkern 1mu} \mathop \to \limits^{{O_2},\,{t^o}} {\mkern 1mu} {\mkern 1mu} \bar nC{O_2}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} + {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \frac{{2\bar n{\mkern 1mu} + 3}}{2}{\mkern 1mu} {H_2}O{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} + {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \frac{1}{2}{\mkern 1mu} {N_2}}\\ {}&{mol:{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} 0,1{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} 0,2{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} } \end{array}\)
Ta có: \(0,2\bar n{\mkern 1mu} = {\mkern 1mu} 0,1.\frac{{2\bar n{\mkern 1mu} + {\mkern 1mu} 3}}{2}{\mkern 1mu} \Rightarrow {\mkern 1mu} \bar n{\mkern 1mu} = {\mkern 1mu} 1,5\)
Vậy công thức phân tử của 2 amin là CH5N và C2H7N
